Writing A Balanced Ionic Equation


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Writing Chemical Equations
Molar Volume, Avogadro’s Law
Chemistry Lessons

In these lessons, we will learn how to write balanced ionic equations.
Writing ionic equations is a fundamental skill in chemistry, particularly when dealing with reactions in aqueous solutions involving ionic compounds.




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How To Write An Ionic Equation From A Word Equation?

When writing an ionic equation, state symbols of the substances must be clearly indicated. Only ionic compounds which are soluble in water (forming aqueous solution) will dissociate into ions in water. Insoluble substance cannot dissociate into ions in water.

The following diagram shows how to write the ionic equation for the reaction of aqueous sodium carbonate with aqueous barium nitrate. Scroll down the page for more examples and solutions on writing ionic equations.

Ionic Equation

Steps to Write Net Ionic Equations

  1. Write the Balanced Molecular Equation:
    This is the standard chemical equation showing the formulas of all reactants and products.
    Ensure the equation is balanced according to the law of conservation of mass (same number of each type of atom on both sides).
    Include the states of matter for each substance: (s) for solid, (l) for liquid, (g) for gas, and (aq) for aqueous (dissolved in water).
  2. Write the Complete Ionic Equation
    Split soluble (aq) compounds into ions.
    Split strong acids and strong bases into ions.
    Keep solids (s), liquids (l), gases (g) intact.
  3. Identify and Remove Spectator Ions
    Identify spectator ions that do not change during the reaction and cross them out.
  4. Write the Net Ionic Equation
    Keep only the reacting ions and products

Important Notes:

  • Know your solubility rules: This is crucial for determining which ionic compounds are soluble and will dissociate.
  • Memorize strong acids and bases: This will help you write the complete ionic equation correctly.
  • Pay attention to states of matter: Only aqueous strong electrolytes are written as ions.
  • Double-check balancing: Ensure both the molecular and ionic equations are balanced in terms of atoms and charges.

Example:
Write the ionic equation for the word equation

Sodium chloride(aq) + silver nitrate(aq) → silver chloride(s) + sodium nitrate(aq)

Solution:
Step 1: Write the equation and balance it if necessary
NaCl(aq) + AgNO3(aq) → AgCl(s) + NaNO3(aq)

Step 2: Split the ions. (Only compounds that are aqueous are split into ions.)
Na+(aq) + Cl-(aq) + Ag+(aq) + NO3-(aq) → AgCl(s) + Na+(aq) + NO3-

Step 3: Cancel out spectator ions. (Spectator ions are ions that remain the same in their original states before and after a chemical reaction.)

Ionic Equation

Step 4: Write a balanced ionic equation
Ag+(aq) + Cl-(aq) → AgCl(s)




Example:
Write the ionic equation for the word equation

Sodium(s) + hydrochloric acid(aq) -> sodium chloride(aq) + hydrogen(g)

Solution:
Step 1: Write the equation and balance it.
2Na(s) + 2HCl(aq) -> 2NaCl(aq) + H2(g)

Step 2: Split the ions. (Only compounds that are aqueous are split into ions.)
2Na(s) + 2H+(aq) + 2Cl-(aq) → 2Na+(aq) + 2Cl-(aq) + H2(g)

Step 3: Cancel out spectator ions. (Spectator ions are ions that remain the same in their original states before and after a chemical reaction.)


Step 4: Write a balanced ionic equation
2Na(s) + 2H+(aq) → 2Na+(aq) + H2(g)

How To Write An Ionic Equation?

Example:
Zinc + Hydrogen Chloride → Zinc Chloride + Hydrogen

How To Write Ionic And Net Ionic Equations?

Example:
Write a complete, total ionic and net ionic equations for the reaction of aqueous sodium carbonate with aqueous barium nitrate.



Molecular, Complete Ionic, and Net Ionic Equations

How To Write A Net Ionic Equation (Double Replacement)?

Basic lesson on molecular equations, complete ionic equations, and net ionic equations. All of them are technically correct, but each one is meant to show a different thing.

Example:
AgNO3 + NaBr → AgBr + NaNO3
HCl + KOH → H2O + KCl

Practice Writing Net Ionic Equations

The examples in the video are these:
Ca(NO3)2 + KF (Calcium Nitrate + Potassium Fluoride)
BaCl2 + H2SO4 (Barium Chloride + Sulfuric Acid)
KOH + HC2H3O2 (Potassium Hydroxide + Acetic Acid)
Sr(C2H3O2)2 + Li2S (Strontium Acetate + Lithium Sulfide)
Ca(OH)2 + Na3PO4 (Calcium Hydroxide + Trisodium Phosphate)

Single Replacement Reactions And Net Ionic Equations

How to write the products of a single replacement reaction and find the net ionic equation?

Examples and practice problems
Al + CuCl2 (Aluminum + Coper Chloride)
Zn + HCl (Zinc + Hydrochloric Acid)
Cl2 + NaBr (Chlorine + Sodium Bromide)
Fe + ZnCl2 (Iron + Zinc Chloride)
Na + HF (Sodium + Hydrofluoric acid)

Precipitation Reactions And Net Ionic Equations

How to balance and predict the products of precipitation reaction in addition to writing the net ionic equation?

Notes, examples, and practice problems.
Examples:
AgNO3 + CaCl2 (Silver Nitrate + Calcium Chloride)
Pb(NO3)2 + NaBr (Lead Nitrate + Sodium Bromide)

Net Ionic Equation Examples And Answers

MgCl2 + AgNO2 (Magnesium Chloride + Silver Nitrate)
H2SO4 + NaOH (Sulfuric acid + Sodium Hydroxide)
HF + KOH (Hydrofluoric acid + Potassium Hydroxide)
Na2CO3 + HCl (Sodium Carbonate + Hydrochloric acid)
Ca(NO3)2 + Na2PO4 (Calcium Nitrate + Sodium Phosphate)



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